The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Alkanes+alkyl radicals / Alkyl radicals / t-C4H9,C(CH3)3 / ParkesQuinn(1976)_298K_229nm(max)

DATAFILE: t-C4H9,C(CH3)3_ParkesQuinn(1976)_298K_229nm(max).txt
NAME: 1,1-dimethylethyl radical, tert-butyl radical
FORMULA: t-C4H9,C(CH3)3
AUTHOR(YEAR): ParkesQuinn(1976)
T: 298K
λ: 229nm(max)
BIBLIOGRAPHY: D.A. Parkes and C.P. Quinn, "Study of the spectra and recombination kinetics of alkyl radicals by molecular modulation spectrometry. Part 2. - The recombination of ethyl, isopropyl and t-butyl radicals at room temperature and t-butyl radicals between 250 and 450 K", J. Chem. Soc. Faraday Trans. I 72, 1952-1971 (1976); DOI: 10.1039/F19767201952
COMMENTS: Absorption measurements using the technique of molecular modulation spectrometry; radical sources were 2,2'-azoisobutane and di-t-butyl peroxide in the presence of isobutane

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